Physics of Supramolecular Structures and Devices

Major: Applied Physics and Nanomaterials
Code of subject: 8.105.00.M.033
Credits: 3.00
Department: Applied Physics and Nanomaterials Science
Lecturer: D.Sc. Ivashchyshyn F.O.
Semester: 4 семестр
Mode of study: денна
Learning outcomes: 1. Ability to demonstrate systematic knowledge of modern research methods in the field of applied physics and nanomaterials. 2. Ability to demonstrate in-depth knowledge in the chosen field of research. 3. Apply knowledge and understanding to solve problems of synthesis and analysis of elements and systems characteristic of the chosen field of research. 4. Investigate and model phenomena and processes of varying complexity in solving problems of nanomaterials. 5. Using the acquired research skills, the ability to independently conduct experimental research. 6. Evaluate the feasibility and feasibility of new methods and technologies in the synthesis of nanomaterials and solving problems of applied physics. 7. Argue the choice of methods for solving scientific and applied problems, critically evaluate the results and defend the decisions made.
Required prior and related subjects: Previous disciplines: 1. Technology and Physics of Electronics and Spintronics Nanostructures; 2. Modern Methods of Physical Research. Related and subsequent disciplines 1. Specific Areas of Chemistry; 2. Physics of Condenced State and Quantum-Dimensional Systems.
Summary of the subject: According to its logical construction, the course can be divided into three parts. The first part describes the principles of supramolecular objects of various chemical nature with physical analysis of supramolecular interactions. The "philosophy" of the supramolecular device is covered separately. Based on this, the second part sets out the basic principles and conceptual approaches to the formation of supramolecular ensembles of various architectures: multilayer inorganic / organic nanohybridized clathrates, semiconductor / cavitation hierarchical structures and their intercalates. In the latter perspective, considerable attention is paid to the first identified effects of selective cation - anionic recognition by hierarchical inorganic / cavitation ensembles. After elucidating the basic physical properties of supramolecular ensembles, their behavior in the electric, magnetic, and light wave fields is then consistently elucidated. The third part systematizes and summarizes the latest trends in the theory of supramolecular systems. In particular, the latest effects such as interference blockade of Faraday current formation, quantum reactance of supramolecular hierarchical objects, the appearance of rotating polaron and the mechanisms of operation of devices based on resonant tunneling and other quantum mechanical effects are analyzed for the first time. Theoretical models for quantum-dimensional N-barrier structures and nanogenerators of electric energy are organically intertwined in this information.
Assessment methods and criteria: Current control (40%): oral questioning, presentations at seminars, tests, individual written work. - The final test (60%): exam.
Recommended books: 1. Hryhorchak I. I., Lukiianets B A., Pidluzhna A. Yu., Politanskyi L. F., Ponedilok H. V., Samila A. P., Khandozhko O. H. Fizychni protsesy u suprmolekuliarnykh ansambliakh ta yikh praktychne zastosuvannia // monohrafiia za red. I. I. Hryhorchaka. – Chernivtsi: Chernivetskyi nats. un-t, 2016. – 536 s. 2. Hryhorchak I. I., Kostrobii P. P., Stasiuk I. V., Tokarchuk M. V., Velychko O. V., Ivashchyshyn F. O., Markovych B. M. Fizychni protsesy ta yikh mikroskopichni modeli v periodychnykh neorhanichno/orhanichnykh klatratakh: Monohrafiia/Hryhorchak I. I. ta in. – Lviv. Vydavnytstvo Rastr-7, 2015. – 286 s. 3. Zenon Hotra, Ivan Hryhorchak, Bohdan Lukiianets, Viktor Makhnii, Serhii Pavlov, Leonid Politanskyi, Ezhy Potenski. Submikronni ta nanorozmirni struktury elektroniky: Pidruchnyk. – Chernivtsi: Vydavnytstvo ta drukarnia «Tekhnolohichnyi Tsentr». 2014. - 839 s.