Supramolecular Devices: Technology and Physics of Processes

Major: Applied Physics and Nanomaterials
Code of subject: 6.105.00.M.068
Credits: 6.00
Department: Applied Physics and Nanomaterials Science
Lecturer: Unknown
Semester: 6 семестр
Mode of study: денна
Learning outcomes: 1. To know the fundamental differences between the structure of supramolecules from the usual macromolecules, as well as the difference between the clathrate principle of the organization of matter from the known daltonid and bertolidny. 2. Know the basic modern methods of formation of supramolecular objects and ensembles and put them into practice. 3. Know the basic conceptual approaches to the supramolecular design of substances and devices. 4. To know the physical properties of supramolecular structures and the features of their manifestation in external physical fields. 5. To be able to synthesize supramolecular ensembles of a given level of architecture hierarchy, to carry out their experimental and theoretical analyzes. 6. To be able to create supramolecular electronics and supramolecular energy devices on their basis.
Required prior and related subjects: Solid state physics Thermodynamics and Statistical Physics
Summary of the subject: By its logical construction, the course can be divided into three parts. The first part presents the beginnings of the supramolecular objects of various chemical nature with the physical analysis of supramolecular interactions. The "philosophy" of the supramolecular device is highlighted separately. Based on this, the second part sets out the basic principles and conceptual approaches to the formation of supramolecular ensembles of various architectures: multilayer inorganic / organic nanohybridized clathrates, semiconductor / cavitand hierarchical structures and their intercalates. In the last perspective, considerable attention is given to the first identified effects of selective cation - anion recognition by hierarchical inorganic / cavitant ensembles. After finding out the basic physical properties of supramolecular ensembles, their behavior in electric, magnetic, and light wave fields is subsequently consistently illuminated. In the third part, the most recent tendencies in the theory of supramolecular systems are systematized and summarized. In particular, for the first time such new effects as the interference blockade of Faraday current formation, quantum reactance of supramolecular hierarchical objects, appearance of a rotating polaron are analyzed, and mechanisms of operation of devices based on resonant tunneling and other quanta are analyzed. This information organically intertwines theoretical models for quantum-sized N-barrier structures and nanogenerators of electricity.
Assessment methods and criteria: Credit, dialogic speech, control test, differentiated test. - current control: (40 %): dialogic speech (20%), control test (10%), differentiated test (10%); - final control (60%): credit – written component (50%), oral component (10%).
Recommended books: 1. Grygorchak I.I., Lukianets B.A., Pidluzhna A. Yu., Politanskii LF, Ponedilok G.V., Samila A.P., Khandozhko O.G. Physical processes in suprmolecular ensembles and their practical application // monograph edited. Grigorchak I.I. - Chernivtsi: Chernivtsi Nat. Univ., 2016 - 536 p. 2. Grygorchak I.I., Kostrobiy P.P., Stasyuk I.V., Tokarchuk M.V., Velychko O.V., Ivashchyshyn F.O., Markovych B.M. Physical processes and their microscopic models in periodic inorganic / organic clathrates: Monograph / Grygorchak I.I. and others. - Lviv. Raster-7 Publishing House, 2015. - 286 p. 3. Zenon Gotra, Ivan Grygorchak, Bogdan Lukianets, Victor Makhni, Sergey Pavlov, Leonid Politanskiy, Jerzy Potenski. Submicron and nanoscale electronics structures: A textbook. - Chernivtsi: Technology Center Publishing House and Printing House. 2014 - 839 p.